PRIMERA DIVISIÓN 2013-2014 Jornada 21
| Pt | MP | W | D | L | F | A | GD | |||
| 1 | FC Barcelona | 54 | 21 | 17 | 3 | 1 | 57 | 13 | 44 | CL |
| 2 | Atlético de Madrid | 54 | 21 | 17 | 3 | 1 | 52 | 14 | 38 | CL |
| 3 | Real Madrid | 53 | 21 | 17 | 2 | 2 | 60 | 21 | 39 | CL |
| 4 | Athletic Club | 42 | 21 | 13 | 3 | 5 | 41 | 27 | 14 | CL |
| 5 | Villarreal CF | 37 | 21 | 11 | 4 | 6 | 39 | 22 | 17 | EL |
| 6 | Real Sociedad | 36 | 21 | 10 | 6 | 5 | 42 | 30 | 12 | EL |
| 7 | Sevilla FC | 31 | 21 | 8 | 7 | 6 | 39 | 34 | 5 | |
| 8 | Levante UD | 27 | 21 | 7 | 6 | 8 | 22 | 30 | -8 | |
| 9 | RCD Espanyol | 26 | 21 | 7 | 5 | 9 | 25 | 27 | -2 | |
| 10 | Valencia CF | 25 | 21 | 7 | 4 | 10 | 28 | 33 | -5 | |
| 11 | Granada CF | 24 | 21 | 7 | 3 | 11 | 19 | 27 | -8 | |
| 12 | Getafe CF | 24 | 21 | 7 | 3 | 11 | 22 | 34 | -12 | |
| 13 | RC Celta | 22 | 21 | 6 | 4 | 11 | 27 | 34 | -7 | |
| 14 | CA Osasuna | 22 | 21 | 6 | 4 | 11 | 18 | 34 | -16 | |
| 15 | UD Almería | 22 | 21 | 6 | 4 | 11 | 22 | 40 | -18 | |
| 16 | Málaga CF | 21 | 21 | 5 | 6 | 10 | 19 | 27 | -8 | |
| 17 | Elche CF | 21 | 21 | 5 | 6 | 10 | 19 | 32 | -13 | |
| 18 | Real Valladolid | 19 | 21 | 4 | 7 | 10 | 24 | 37 | -13 | 2a |
| 19 | Rayo Vallecano | 16 | 21 | 5 | 1 | 15 | 21 | 51 | -30 | 2a |
| 20 | Real Betis Balompié | 11 | 21 | 2 | 5 | 14 | 18 | 47 | -29 | 2a |
| Jornada 20 « || Jornada 21 || » Jornada 22 |
PRIMERA DIVISIÓN 2013-2014 Jornada 21
2014/01/24
| 21:00 | Balaídos | ||
| RC Celta | 4-2 | Real Betis Balompié |
| 0-1 | 17' Rubén Castro | |
| F.Orellana 22' | 1-1 | |
| Charles 31' | 2-1 | |
| F.Orellana 39' | 3-1 | |
| Nolito 73' | 4-1 | |
| 4-2 | 78' Rubén Castro | |
2014/01/25
| 16:00 | Santiago Bernabéu | ||
| Real Madrid | 2-0 | Granada CF |
| Cristiano Ronaldo 56' | 1-0 | |
| K.Benzema 74' | 2-0 | |
| 18:00 | Nuevo José Zorrilla | ||
| Real Valladolid | 1-0 | Villarreal CF |
| Jesús Rueda 40' | 1-0 | |
| 20:00 | Mestalla | ||
| Valencia CF | 2-2 | RCD Espanyol |
| 0-1 | 3' J.Córdoba | |
| Paco Alcácer 7' | 1-1 | |
| Jonas 32' | 2-1 | |
| 2-2 | 45' Sergio García (pen) | |
| 22:00 | Ramón Sánchez Pizjuán | ||
| Sevilla FC | 2-3 | Levante UD |
| Coke 26' | 1-0 | |
| 1-1 | 30' David Barral (pen) | |
| I.Rakitić 68' | 2-1 | |
| 2-2 | 71' L.Vyntra | |
| 2-3 | 75' Simão Junior | |
2014/01/26
| 12:00 | Estadio del Mediterráneo | ||
| UD Almería | 1-0 | Getafe CF |
| J.Zongo 49' | 1-0 | |
| 17:00 | El Sadar | ||
| CA Osasuna | 1-5 | Athletic Club |
| 0-1 | 3' Susaeta | |
| E.Armenteros 10' | 1-1 | |
| 1-2 | 16' Aduriz | |
| 1-3 | 62' Aduriz | |
| 1-4 | 84' Ibai | |
| 1-5 | 88' Kike Sola | |
| 19:00 | Campo de Vallecas | ||
| Rayo Vallecano | 2-4 | Atlético de Madrid |
| 0-1 | 8' David Villa | |
| 0-2 | 30' A.Turan | |
| Jonathan Viera 39' | 1-2 | |
| 1-3 | 44' A.Turan | |
| 1-4 | 74' OG (Saúl Ñíguez) | |
| J.Larrivey 75' | 2-4 | |
| 21:00 | Camp Nou | ||
| FC Barcelona | 3-0 | Málaga CF |
| Gerard Piqué 40' | 1-0 | |
| Pedro Rodríguez 55' | 2-0 | |
| A.Sánchez 61' | 3-0 | |
2014/01/27
| 22:00 | Anoeta | ||
| Real Sociedad | 4-0 | Elche CF |
| OG (D.Suárez) 3' | 1-0 | |
| A.Griezmann 12' | 2-0 | |
| C.Vela 50' | 3-0 | |
| A.Griezmann 74' | 4-0 | |