PRIMERA DIVISIÓN 2013-2014 Jornada 5
| Pt | MP | W | D | L | F | A | GD | |||
| 1 | FC Barcelona | 15 | 5 | 5 | 0 | 0 | 18 | 4 | 14 | CL |
| 2 | Atlético de Madrid | 15 | 5 | 5 | 0 | 0 | 16 | 4 | 12 | CL |
| 3 | Real Madrid | 13 | 5 | 4 | 1 | 0 | 12 | 5 | 7 | CL |
| 4 | Villarreal CF | 11 | 5 | 3 | 2 | 0 | 10 | 5 | 5 | CL |
| 5 | RCD Espanyol | 11 | 5 | 3 | 2 | 0 | 9 | 5 | 4 | EL |
| 6 | Athletic Club | 9 | 5 | 3 | 0 | 2 | 10 | 9 | 1 | EL |
| 7 | Real Sociedad | 6 | 5 | 1 | 3 | 1 | 4 | 3 | 1 | |
| 8 | RC Celta | 6 | 5 | 1 | 3 | 1 | 7 | 7 | 0 | |
| 9 | Valencia CF | 6 | 5 | 2 | 0 | 3 | 8 | 10 | -2 | |
| 10 | Levante UD | 6 | 5 | 1 | 3 | 1 | 4 | 10 | -6 | |
| 11 | Málaga CF | 5 | 5 | 1 | 2 | 2 | 7 | 4 | 3 | |
| 12 | Real Betis Balompié | 5 | 5 | 1 | 2 | 2 | 5 | 5 | 0 | |
| 13 | Granada CF | 5 | 5 | 1 | 2 | 2 | 3 | 4 | -1 | |
| 14 | Real Valladolid | 4 | 5 | 1 | 1 | 3 | 3 | 6 | -3 | |
| 15 | Getafe CF | 4 | 5 | 1 | 1 | 3 | 5 | 10 | -5 | |
| 16 | UD Almería | 3 | 5 | 0 | 3 | 2 | 10 | 13 | -3 | |
| 17 | Elche CF | 3 | 5 | 0 | 3 | 2 | 4 | 8 | -4 | |
| 18 | CA Osasuna | 3 | 5 | 1 | 0 | 4 | 4 | 10 | -6 | 2a |
| 19 | Rayo Vallecano | 3 | 5 | 1 | 0 | 4 | 4 | 16 | -12 | 2a |
| 20 | Sevilla FC | 2 | 5 | 0 | 2 | 3 | 6 | 11 | -5 | 2a |
| Jornada 4 « || Jornada 5 || » Jornada 6 |
PRIMERA DIVISIÓN 2013-2014 Jornada 5
2013/09/20
| 21:00 | El Sadar | ||
| CA Osasuna | 2-1 | Elche CF |
| E.Armenteros 16' | 1-0 | |
| Oriol Riera 48' | 2-0 | |
| 2-1 | 88' Edu Albácar (pen) | |
2013/09/21
| 16:00 | Anoeta | ||
| Real Sociedad | 0-0 | Málaga CF |
| 18:00 | Estadio del Mediterráneo | ||
| UD Almería | 2-2 | Levante UD |
| Verza (pen) 45+3' | 1-0 | |
| Suso 51' | 2-0 | |
| 2-1 | 55' N.El Zhar (pen) | |
| 2-2 | 60' P.Diop | |
| 20:00 | Campo de Vallecas | ||
| Rayo Vallecano | 0-4 | FC Barcelona |
| 0-1 | 33' Pedro Rodríguez | |
| 0-2 | 47' Pedro Rodríguez | |
| 0-3 | 72' Pedro Rodríguez | |
| 0-4 | 80' Cesc Fàbregas | |
| 22:00 | Nuevo José Zorrilla | ||
| Real Valladolid | 0-2 | Atlético de Madrid |
| 0-1 | 56' Raúl García | |
| 0-2 | 72' Diego Costa | |
2013/09/22
| 12:00 | Benito Villamarín | ||
| Real Betis Balompié | 0-0 | Granada CF |
| 17:00 | Balaídos | ||
| RC Celta | 0-0 | Villarreal CF |
| 19:00 | Santiago Bernabéu | ||
| Real Madrid | 4-1 | Getafe CF |
| 0-1 | 5' Lafita | |
| Pepe 19' | 1-1 | |
| Cristiano Ronaldo (pen) 34' | 2-1 | |
| Isco Alarcón 59' | 3-1 | |
| Cristiano Ronaldo 90+3' | 4-1 | |
| 21:00 | Mestalla | ||
| Valencia CF | 3-1 | Sevilla FC |
| Jonas 32' | 1-0 | |
| 1-1 | 52' K.Gameiro | |
| Jonas 73' | 2-1 | |
| Víctor Ruíz 82' | 3-1 | |
2013/09/23
| 22:00 | Cornellà-El Prat | ||
| RCD Espanyol | 3-2 | Athletic Club |
| Víctor Sánchez 24' | 1-0 | |
| 1-1 | 44' De Marcos | |
| Víctor Sánchez 49' | 2-1 | |
| Sergio García 66' | 3-1 | |
| 3-2 | 90+2' Ibai | |